期刊
PHYSICAL REVIEW B
卷 72, 期 4, 页码 -出版社
AMERICAN PHYSICAL SOC
DOI: 10.1103/PhysRevB.72.045216
关键词
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The exciton diffusion process in a poly(p-phenylene vinylene)- (PPV-)based derivative is investigated using time-resolved photoluminescence in conjugated polymer/fullerene heterostructures. The decay of the luminescence in the polymer/fullerene heterostructures is governed by exciton diffusion and subsequent dissociation at the polymer/fullerene interface. The decay curves of polymer layers with varying thickness are consistently modeled using an exciton diffusion constant of 3x10(-4) cm(2)/s. The resulting exciton migration radius amounts to 6 nm, which is a measure for the active part of the PPV/fullerene heterojunction for photovoltaic applications.
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