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Rhenium complexes of N-methyl N-confused tetraphenylporphyrin and its normal isomer

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CHEMISTRY LETTERS
卷 34, 期 7, 页码 1034-1035

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CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2005.1034

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The rhenium tricarbonyl complexes bearing tridentate porphyrin ligands, N-methyltatraphenylporphyrin and N-methyl N-confused tatraphenylporphyrin, were prepared and their structures were studied by X-ray crystallographic analysis. Drastic change of HOMO-LUMO gap by confusion of N-methylpyrrole moiety was illustrated from experimental and theoretical studies.

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