期刊
SCIENCE
卷 309, 期 5732, 页码 281-284出版社
AMER ASSOC ADVANCEMENT SCIENCE
DOI: 10.1126/science.1112446
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An organic material composed of neutral free radicals based on the spiro-biphenalenyl system exhibits a room temperature conductivity of 0.3 siemens per centimeter and a high-symmetry crystal structure. It displays the temperature-independent Pauli paramagnetism characteristic of a metal with a magnetic susceptibility that implies a density of states at the Fermi level of 15.5 states per electron volt per mote. Extended Huckel calculations indicate that the solid is a three-dimensional organic metal with a band width of similar to 0.5 electron volts. However, the compound shows activated conductivity (activation energy, 0.054 electron volts) and an optical energy gap of 0.34 electron volts. We argue that these apparently contradictory properties are best resolved in terms of the resonating valence-bond ground state originally suggested by Pauling, but with the modifications introduced by Anderson.
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