期刊
MATERIALS CHEMISTRY AND PHYSICS
卷 92, 期 1, 页码 39-42出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.matchemphys.2004.12.028
关键词
Bi-Te-Se; thermoelectric properties; zone melting
n-Type (Bi2Te3)(0.93)(Bi2Se3)(0.07) thermoelectric materials doped with various content of TeI4 (0, 0.05, 0.10, 0.13, and 0.15 wt.%) have been fabricated through the zone melting method. Electrical conductivity (sigma), Seebeck coefficient (alpha) and thermal conductivity (kappa) were measured along the crystal growth direction in the temperature range of 300-500 K. The influence of the variations of TeI4 content on thermoelectric properties was studied. The undoped (Bi2Te3)(0.93)(Bi2Se3)(0.07) exhibited p-type conduction and it translated to n-type when TeI4 was doped. The increase of TeI4 content increased the carrier concentration and thus resulted in an increase of a and a decrease of vertical bar alpha vertical bar. The maximum figure of merit ZT (ZT = alpha(2)sigma T/kappa) of the zone-melted crystals in the direction parallel to the growth direction showed a value of 0.90 for the sample containing 0.10 wt.% TeI4. (c) 2005 Elsevier B.V. All rights reserved.
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