Raman spectroscopy of single-wall carbon nanotubes and graphite irradiated by γ rays -: art. no. 024311

Graphite and single-wall carbon nanotubes irradiated by gamma rays of energy of 1.3 MeV were investigated by Raman spectroscopy. Irradiation generates defects in the lattice as confirmed by the increase of the intensity of the defect-induced D line in both materials. On the other hand, the intensity of the radial breathing mode of nanotubes is lowered. The intensity of the G line does not change for graphite but increases for carbon nanotubes. For the latter, this behavior cannot be explained by the defect-mediated double-resonance mechanism. Softening of the q=0 selection rule is suggested as a way to explain the results.