期刊
JOURNAL OF SOLID STATE CHEMISTRY
卷 178, 期 8, 页码 2409-2413出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jssc.2005.05.034
关键词
metal-organic; template; polygons; polyhedra; self-assembly; host-guest; metallo-supramolecular
We show how a template-controlled reaction performed in the organic solid state can be used to construct a molecule that functions as an organic building unit of both a metal-organic polyhedron and polygon. The template is a small organic molecule that organizes two olefins via hydrogen bonds for a [2+2] photodimerization. The process of utilizing a molecule to build a molecule that is subsequently used for self-assembly is inspired by the general two-step process of template-directed synthesis and self-assembly of Nature that is used to construct large, functional self-assembled structures. (c) 2005 Elsevier Inc. All rights reserved.
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