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Quantifying carbon-nanotube species with resonance Raman scattering

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PHYSICAL REVIEW B
卷 72, 期 7, 页码 -

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AMERICAN PHYSICAL SOC
DOI: 10.1103/PhysRevB.72.075207

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The method for quantifying the amount of each carbon nanotube specie, as defined by its diameter and chiral angle, as well as the semiconducting-to-metallic ratio in any type of carbon nanotube sample is discussed. Single-wall carbon nanotubes grown by the cobalt-molybdenum catalyst based (CoMoCAT) process are characterized. The semiconducting-to-metallic ratio is found to be 11:1. A single semiconducting specie, named the (6,5) nanotube represents 2/5 of the sample, while the most abundant metallic nanotube is the (7,4), which exhibits a diameter similar to the (6,5).

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