期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 347, 期 10, 页码 1325-1328出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200505113
关键词
carbon dioxide fixation; copolymerization; green chemistry; homogeneous catalysis; ligand design
New 3-amino-2-cyanoimidoacrylate ligands with varying steric demands have been synthesized. Zinc acetate complexes of these ligands catalyze the copolymerisation Of CO2 and cyclohexene oxide, showing high activities (TOF up to over 200 h (-1)).
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