期刊
EUROPEAN POLYMER JOURNAL
卷 41, 期 8, 页码 1757-1765出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.eurpolymj.2005.02.026
关键词
poly(oligo(ethylene glycol) methacrylate) (POEGMA); atom transfer radical polymerization (ATRP); protein resistance
Here we report a study into controlling the polymerization of mono-hydroxy and mono-methoxy terminated oligo(ethylene glycol) methacrylates (HOEGMA and MeOEGMA, respectively) from functionalised, planar surfaces via atom transfer radical polymerization (ATRP). The effects of initiator structure, initiator density, temperature, and monomer ratios have been investigated for these polymerizations. The polymer brushes grown in this way were found to convey protein resistance to the underlying inorganic substrates, prone to facile protein adsorption in their native state. (c) 2005 Elsevier Ltd. All rights reserved.
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