期刊
ORGANIC LETTERS
卷 7, 期 16, 页码 3573-3575出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol0513903
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资金
- NHLBI NIH HHS [F32 HL080565] Funding Source: Medline
A turn-on fluorescent sensor for NO (g) in solution was synthesized using a bipyridyl-substituted poly(p-phenylene vinylene) derivative (CP1) as the sensory scaffold. The action of NO (g) upon the CP1-Cu(II) complex reduces it to the CP1-Cu(l) complex with a concomitant 2.8-fold increase in emission intensity. The reagent is selective for NO (g) versus other biological reactive nitrogen species, except for nitroxyl, and has a detection sensitivity limit of 6.3 nM.
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