期刊
CHEMPHYSCHEM
卷 6, 期 8, 页码 1483-1491出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cphc.200500190
关键词
C-13 satellite spectra; conformation analysis; liquid crystals; NMR spectroscopy; vibrational corrections
The proton NMR spectra of samples of 2-thiophenecarboxalde-hyde dissolved in a nematic liquid crystalline solvent, including those from all five singly labelled C-13 isotopomers, have been obtained. These have been analysed to yield sets of partially averaged dipolar couplings which have been used to determine the structure and the relative amounts of the cis and trans forms, which are the two minimum-energy structures generated by rotation about the ring-aldehyde bond. A procedure for applying vibrational corrections to the dipolar couplings in the presence of large amplitude motions is discussed.
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