期刊
JOURNAL OF CATALYSIS
卷 234, 期 1, 页码 111-118出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcat.2005.05.023
关键词
Sn-beta; DFT calculations; IR spectroscopy; Lewis acidity; acetonitrile adsorption; Baeyer-Villiger; deep and shallow bed calcinations
Two types of Lewis acid sites are shown to exist in Sn-beta zeolite: partially hydrolysed framework tin centers (-Si-O-)(3)Sn-OH (sites A) and fully framework coordinated tin atoms Sn(-Si-O-)(4) (sites B). ONIOM and DFT calculations for adsorbed acetonitrile, which is a probe molecule for Lewis acid sites, show that acetonitrile coordinates more strongly to partially hydrolysed framework Sn (sites A) in Sn-beta zeolite than to nonhydrolysed framework Sn (sites B). The corresponding IR bands associated with the v(C equivalent to N) stretching vibration were also calculated. Adsorption-desorption experiments of deuterated acetonitrile on Sn-beta give two IR bands at 2316 and 2308 cm(-1) with IR shifts of 43 and 51 cm(-1) with respect to gas-phase acetonitrile. These values are in excellent agreement with theoretical calculations, making it possible then to associate the Lewis sites related to 2316 and 2308 cm(-1) with partially hydrolysed and nonhydrolysed framework Sn sites, respectively. Catalytic results confirm that partially hydrolysed Sn (sites A) is much more active than fully framework-integrated Sn (sites B) for Baeyer-Villiger oxidation of cyclic ketones. Finally, the ratio between these two types of sites could be influenced by postsynthesis treatments. (c) 2005 Elsevier Inc. All rights reserved.
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