期刊
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
卷 78, 期 8, 页码 1401-1410出版社
CHEMICAL SOC JAPAN
DOI: 10.1246/bcsj.78.1401
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Various arylbis(trifluoromethylsulfonyl)methanes (1) have been synthesized by reacting the corresponding benzylic halides with sodium trifluoromethanesulfinate and then with triflic anhydride. In addition, when the aryl group of 1 is a pentafluorophenyl group, the nucleophilic para-substitution of the aryl group with alkyllithiums and sodium alkoxides occurs. This reaction is useful for the design of new Bronsted acids.
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