4.7 Article

Acrylic acid reversed polyHIPEs

期刊

MACROMOLECULAR RAPID COMMUNICATIONS
卷 26, 期 16, 页码 1289-1293

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/marc.200500353

关键词

hydrophilic polymers; macroporous polymers; poly(acrylic acid); polyHIPE; supports

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An oil-in-water high internal phase emulsion consisting of acrylic acid, water, and a crosslinker (N,N'-methylene bisacrylamide) as the water phase, and toluene as the oil phase was successfully stabilised to sustain thermal initiation of radical polymerisation resulting in porous open-cellular monolithic material. The type of initiator used influenced the average pore size ranging from approx, 708 nm to approx, 1 087 nm, as determined by mercury porosimetry.

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