期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 11, 期 17, 页码 4935-4952出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.200500160
关键词
metathesis; natural products; solid-phase synthesis; total synthesis
A modular synthesis for pochonin C and radicicol is reported. The two natural products were prepared in seven and eight steps, respectively, from three readily available fragments. Alternative syntheses of these compounds were achieved using a combination of polymer-bound reagents and solid phase reactions. The conformation of the two natural products was studied and compared by using 2D NMR spectroscopy.
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