Lithium intercalation into α-Fe2O3 obtained by mechanical milling of α-FeOOH

Crystalline alpha-Fe2O3 powder was prepared by the mechanical milling of crystalline alpha-FeOOH at room temperature in air. This result means that crystalline alpha-Fe2O3 is dehydrated by mechanical milling at room temperature. The obtained alpha-Fe2O3 powder worked as a rechargeable electrode material in lithium ion conductive organic electrolytes. The electrodes exhibited high discharge capacities of over 1000 mAh g(-1) corresponding to 6 Li per alpha-Fe2O3 at potentials ranging from the open circuit potential to 0.5 V (versus Li+/Li) in the first discharging (lithium insertion) process. This suggests that the valence deviation from Fe3+ in alpha-Fe2O3 to Fe-0 may be caused by electrochemical reduction. In contrast, after the first discharge, the electrodes exhibited high charge capacities of more than 700 mAh g(-1) corresponding to 4.2 Li per alpha-Fe2O3 in the first charging (lithium extraction) process. The coulombic efficiency at the first cycle was about 70%, suggesting a valence deviation from Fe-0 to Fe2+ or Fe3+ caused by electrochemical oxidation. (c) 2005 Elsevier B.V. All rights reserved.