期刊
JOURNAL OF POWER SOURCES
卷 146, 期 1-2, 页码 534-538出版社
ELSEVIER
DOI: 10.1016/j.jpowsour.2005.03.058
关键词
LiFePO4; cathode material; olivine-type iron phosphate; mechanical alloying
Olivine LiFePO4 has been produced using Fe2O3 raw material by mechanical alloying (MA) and subsequent firing. X-ray diffraction (XRD) and Mossbauer spectroscopy analysis revealed that LiFePO4 prepared by MA had a well-ordered olivine-type LiFePO4 Structure with an ionic state of Fe2+ by the reduction of Fe3+ precursor. It showed a maximum discharge capacity of 160 mAh g(-1) at C/20 (8.5 mA g(-1)) when cycled from 2.5 to 4.3 V. Compared to the LiFePO4 prepared by conventional solid-state method, MA synthesized LiFePO4 a displayed higher charge/discharge capacity and more stable cycle life because of the improvement of the electronic conductivity. It was originated from uniformly distributed fine particles and an increased specific surface area by MA process. (c) 2005 Elsevier B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据