期刊
CRYSTAL GROWTH & DESIGN
卷 5, 期 5, 页码 1837-1843出版社
AMER CHEMICAL SOC
DOI: 10.1021/cg050100m
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Crystallization of three new organic/inorganic hybrid solids (1-3) based on octamolybdate under self-assembly conditions has demonstrated the structure-directing role of three hydrogen-bonded organic dimers (supramolecular synthons) in the construction of multidimensional networks. In acidified aqueous molybdate solution, isomeric phenylenediammonium ions form dimers through strong hydrogen-bonding and/or pi-pi interactions, which in turn dictate the supramolecular assemblies between themselves or with octamolybdate anions that eventually result in the growth of hybrid solids.
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