期刊
CRYSTAL GROWTH & DESIGN
卷 5, 期 5, 页码 1913-1917出版社
AMER CHEMICAL SOC
DOI: 10.1021/cg050184z
关键词
-
The directed synthesis of two noncentrosymmetric sulfated molybdates has been achieved through the use of chiral organic amines. Reaction gels containing either (R)-2-methylpiperazine or (S)-2-methylpiperazine, MoO3, H2SO4, and H2O were subjected to mild hydrothermal conditions, resulting in the growth of single crystals of [(R)-C5H14N2][(MoO3)(3)(SO4)](H2O)-H-. and [(S)-C5H14N2][(MoO3)(3)(SO4)](H2O)-H-.. These materials crystallize in the noncentroysmmetric space group P2(1)2(1)2(1) (No. 19), which exhibits the enantiomorphic crystal class 222 (D-2). The second harmonic generation activities were measured on sieved powders.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据