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Density functional approach for inhomogeneous star polymer fluids

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PHYSICAL REVIEW E
卷 72, 期 3, 页码 -

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AMER PHYSICAL SOC
DOI: 10.1103/PhysRevE.72.032801

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We propose microscopic density functional theory for inhomogeneous star polymer fluids. Our approach is based on fundamental measure theory for hard spheres, and on Wertheim's first- and second-order perturbation theory for the interparticle connectivity. For simplicity we consider a model in which all the arms are of the same length, but our approach can be easily extended to the case of stars with arms of arbitrary lengths.

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