We propose a method to create superpositions of two macroscopic quantum states of a single-mode microwave cavity field interacting with a superconducting charge qubit. The decoherence of such superpositions can be determined by measuring either the Wigner function of the cavity field or the charge qubit states. Then the quality factor Q of the cavity can be inferred from the decoherence of the superposed states. The proposed method is experimentally realizable within current technology even when the Q value is relatively low and the interaction between the qubit and the cavity field is weak.
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