期刊
TETRAHEDRON LETTERS
卷 46, 期 37, 页码 6389-6393出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2005.05.101
关键词
electrolysis; stereoselectivity; electrocatalytic transformation; mediators; malonate; arylidenemalononitriles; bicyclic pyrrolidones
Electrolysis of arylidene- or alkylidenemalononitriles and malonate in alcohol in an undivided cell in the presence of sodium halide as mediator results in the stereoselective formation of alkyl (IR,5R,6R)* 6-substituted 5-cyano-4,4-dialkoxy-2oxo-3-azabicyclo[3.1.0]hexan-1-carboxylates in 50-70% yields. (c) 2005 Elsevier Ltd. All rights reserved.
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