期刊
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卷 7, 期 19, 页码 4297-4300出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol051849t
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资金
- PHS HHS [50771] Funding Source: Medline
A consise stereoselective total synthesis of a naturally occurring polymerase beta inhibitor, delta-trans-tocotrienoloic acid (2), is described. The key step in the synthesis is an acid-catalyzed cyclodehydration reaction. Additionally, this report corrects a previously reported structural assignment, defines the absolute stereochemistry of 2, and defines key structural requirements for polymerase beta inhibition.
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