期刊
CHEMISTRY OF MATERIALS
卷 17, 期 19, 页码 4837-4844出版社
AMER CHEMICAL SOC
DOI: 10.1021/cm051264t
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The chemical compositions at the surface and in the bulk of the sol-gel-derived ZrO2 films calcined at elevated temperatures in air or in N-2 atmospheres were examined to understand the metastability of the tetragonal phase and the mechanism of its phase transformation. The phase evolution of ZrO2 in air followed the sequence of amorphous -> m-tetragonal -> monoclinic over 80-950 degrees C, while the phase transformation of amorphous -> m-tetragonal -> monoclinic -> m-tetragonal was observed under N-2 atmosphere. The reduction of Zr4+ to low-valent states and the generation of oxygen vacancies via dehydroxylation and deoxygenation play the crucial roles in stabilizing m-tetragonal ZrO2 in the Solgel-derived films. The O/Zr ratios for stabilizing the m-tetragonal ZrO2 ranged between 1.98 and 1.63. The m-tetragonal-to-monoclinic phase transformation primarily involves the segregation of lattice defects to grain boundaries and occupation of oxygen vacancies by the diffused O2- ions that were converted from surface hydroxyl groups. In the absence of alternative oxygen donors, including water and oxygen molecules, the stability of m-tetragonal ZrO2 was maintained at elevated temperatures under N-2 atmosphere. In addition, regeneration of the oxygen vacancies via deoxygenation at high temperature results in the reformation of m-tetragonal ZrO2. The changes in the chemical compositions and crystallite sizes of the films depict that the m-tetragonal-to-monoclinic phase transformation starts from the core of tetragonal domains, while its retransformation begins from the boundaries of monoclinic grains.
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