期刊
TETRAHEDRON LETTERS
卷 46, 期 39, 页码 6651-6653出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2005.07.162
关键词
Keck allylation; intramolecular oxy-Michael reaction; (-)-centrolobine; 2,6-disubstituted tetrahydropyran
An expedient total synthesis of (-)-centrolobine is achieved involving asymmetric Keck allylation and stereoselective intramolecular oxy-Michael reactions as key steps in 8% overall yield. (c) 2005 Published by Elsevier Ltd.
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