期刊
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
卷 43, 期 19, 页码 4570-4577出版社
WILEY
DOI: 10.1002/pola.20933
关键词
aromatic polyesters; carbohydrate-based monomers; polycondensation
The synthesis and characterization of a new series of aromatic polyesters based on D-mannitol and galactitol are described. These polyesters were obtained by polycondensation reaction of the terephthaloyl chloride or isophthaloyl chloride and 2,3,4,5-tetra-O-methyl-D-mannitol or 2,3,4,5-tetra-O-methyl-galactitol in o-dichlorobenzene. All the new polyesters were characterized by elemental analyses, GPC, IR, and NMR. They were soluble in chloroform, but insoluble in water and other polar oxygenated solvents. They showed a notable hygroscopicity, lower for those containing isophthalic units. DSC and X-ray diffraction studies showed that D-mannitol-based polyesters were stiffer and less crystalline than those derived from galactitol, which presented a noticeably lower thermal stability. (c) 2005 Wiley Periodicals, Inc.
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