期刊
CHEMISTRY LETTERS
卷 34, 期 10, 页码 1456-1457出版社
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2005.1456
关键词
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In the presence of AlCl3, trimethylsilyl cyanide underwent 1,4- and subsequent 1,2-additions with alpha,beta-unsaturated imines to give 2-aminopentanedinitriles in good yields. An asymmetric version of this type of bis-cyanation was successfully conducted using a chiral alpha,beta-unsaturated imine possessing a phenylglycinol derivative as a chiral auxiliary.
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