期刊
JOURNAL OF APPLIED POLYMER SCIENCE
卷 98, 期 1, 页码 189-194出版社
WILEY
DOI: 10.1002/app.22041
关键词
water-soluble polymers; glycopolymers; polyacrylamides; atom transfer radical polymerization (ATRP); functionalization of polymers
Poly(N-acryloxysuccinimide) (polyNAS) with narrow molecular weight distributions (MWD) applicable for the preparation of well-defined glycoconjugate polyacrylamides were successfully prepared by atom transfer radical polymerization (ATRP). The structures of polyNAS were characterized by H-1-NMR and GPC. GPC results showed that the molecular weight polydispersity indices (PDI) range from 1.17 to 1.29. The molecular weights could be calculated based on H-1-NMR results but GPC results of polyNAS by using 0.01M LiBr/DMF did not give accurate molecular weights, probably because of the complex interaction in the system. The effects of free N-hydroxysuccimide produced in the polymerization processes on the free-radical concentrations and apparent initiation efficiencies of ATRP were discussed. Well-defined glycoconjugate polyacrylamides (i.e., with narrow molecular weight distributions and designed glycoconjugate degrees) were prepared by substituting N-oxysuccimide units with galactosamine followed by reaction of ethanolamine. The galactose conjugate degrees were determined by H-1-NMR and the total substitutions of N-oxysuccimides were verified by H-1-NMR and FTIR. (c) 2005 Wiley Periodicals, Inc.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据