期刊
TETRAHEDRON LETTERS
卷 46, 期 41, 页码 7037-7042出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2005.08.051
关键词
amines; Hagemann's ester; organocatalysis; push-pull dienamine; tandem reactions
A new, green, regioselective, one-step, tandem reaction of an aldehyde possessing a non-enolizable carbonyl function with a highly substituted cyclohex-2-enone, under amine catalysis afforded highly substituted phenols or 2-arylidenecyclohexanones, respectively. The yields and regioselectivities were good. Evidence for a pathway involving formation of novel push-pull dienamines is presented along with examples demonstrating the amenability of the process to combinatorial chemistry. (c) 2005 Elsevier Ltd. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据