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卷 7, 期 21, 页码 4549-4552出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol051765k
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- Engineering and Physical Sciences Research Council [GR/S40619/01] Funding Source: researchfish
Oxidation of alkyl and cycloalkyl arenes with tert-butyl hydroperoxide catalyzed by bismuth and picolinic acid in pyridine and acetic acid gave the corresponding benzylic ketones (48-99%). Alternatively, oxidation of methyl arenes gave the corresponding substituted benzoic acids (50-95%). Preliminary mechanistic studies were consistent with a radical mechanism rather than a bismuth(Ill)-bismuth(V) cycle.
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