期刊
PHYSICAL REVIEW LETTERS
卷 95, 期 16, 页码 -出版社
AMER PHYSICAL SOC
DOI: 10.1103/PhysRevLett.95.166101
关键词
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Step edges and low-symmetry faces of metal crystals can restrict the diffusive motion of adsorbates, yet they offer little flexibility with regards to the location and/or direction of the guided motion. We show inherently unidirectional motion of an organic molecule on a high-symmetry thermodynamic-equilibrium metal surface [Cu(111)]. Sequential placement of the substrate linkers of 9,10-dithioanthracene prevents it from rotating or veering off course. A combination of low temperature scanning tunneling microscopy and density functional theory simulations provide atomistic insight.
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