期刊
JOURNAL OF CATALYSIS
卷 235, 期 2, 页码 423-427出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcat.2005.08.003
关键词
mesoporous titanosilicate; catalytically active titanium species; silylation; hydroxylatiom; epoxidation; Si-29 MAS NMR spectroscopy
Calcined Ti-MCM-41 was silylated by trimethylchlorosilane in the vapor phase for 2-9 h. Si-29 MAS NMR spectroscopic study showed that Ti-MCM-41 silylated for 2-5 h exhibited a peak at 11 ppm, which was assigned to (CH3)(3)SiOSi(OSi)(3) species. Further silylation of Ti-MCM-41 for 5-9 h gave an additional peak at 5.1 ppm, which was assigned to novel titanium species of (CH3)(3)SiOTi(OSi)(3). Ti-MCM-41 silylated for 5 h showed relatively high activity in hydroxylation of benzene and epoxidation of 1-octene compared with calcined Ti-MCM-41. More important, Ti-MCM-41 silylated for 9 h gave much higher activity than Ti-MCM-41 silylated for 5 h. Si-29 MAS NMR spectra showed the presence of the titanium species of (CH3)(3)SiOTi(OSi)(3) in Ti-MCM-41 silylated for 5-9 h. and these can be better catalytically active sites than conventional titanium species in Ti-MCM-41. (c) 2005 Elsevier Inc. All rights reserved.
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