Photosensitized conversion of 9,10-deoxytridachione to photodeoxytridachione

[GRAPHICS] The photochemical conversion of 9,10-deoxytridachione to photodeoxytriclachione has been photosensitized. The conversion was also quenched by piperylene. Photodeoxytridachione was produced in good yields under conditions in which only the cyclohexadiene group is sensitized. The results show that some, and perhaps all, of the photoreactions of 9,10-deoxytridachione occur through a triplet excited state. The mechanistic and biosynthetic implications of these results are discussed.