4.8 Article

Counterions at charged cylinders: Criticality and universality beyond mean-field theory

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PHYSICAL REVIEW LETTERS
卷 95, 期 18, 页码 -

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AMERICAN PHYSICAL SOC
DOI: 10.1103/PhysRevLett.95.185703

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The counterion-condensation transition at charged cylinders is studied using Monte Carlo simulations. Employing logarithmically rescaled radial coordinates, large system sizes are tractable and the critical behavior is determined by a combined finite-size and finite-ion-number analysis. Critical counterion localization exponents are introduced and found to be in accord with mean-field theory both in two (2D) and three (3D) dimensions. In 3D, the heat capacity shows a universal jump at the transition, while in 2D, it consists of discrete peaks where single counterions successively condense.

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