期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 347, 期 14, 页码 1755-1758出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200505130
关键词
asymmetric hydrogenation; immobilization; iridium; phosphinite ligands; poly(ethylene glycol) dimethyl ether; quinoline
The chiral diphosphinite H8-BINAPO derived from H8-BINOL has been used in the Ir-catalyzed asymmetric hydrogenation of quinolines, and high enantioselectivity (up to 97% ee) was obtained. Immobilization of the iridium catalyst in poly(ethylene glycol) dimethyl ether (DMPEG) is also discussed. With DMPEG/hexane biphasic system, better enantioselectivities were obtained as compared to those observed in aprotic organic solvents.
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