期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 127, 期 43, 页码 15107-15111出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja052713t
关键词
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The synthesis of a block codendrimer (g3-PBE-b-g3-PMDC), composed of a third-generation poly(benzyl ether) (PBE) monodendron and an aliphatic polyether (PMDC) monodendron is reported. In THF/diiospropyl ether (1:1) the PMDC block functions as a hydrophilic block, while the PBE acts as a hydrophobic block. The codendrimer can form interdigitated layers leading to vesicle formation. Tapping mode atomic force microscopy (AFM), dynamic light scattering (DLS), and transmission electron microscopy (TEM) were used to characterize the vesicles. The effect of molecular architecture on the formation of the interdigitated layers and vesicles was studied.
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