期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 11, 期 22, 页码 6514-6518出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.200500799
关键词
allenes; allylic compounds; C-C coupling; fluoride; silicates
Reactions of trimethyl(trifluoromethyl)silane in the presence of naked fluoride proceed up to a temperature of +5 degrees C mainly with formation of [Me3Si(CF3)(2)](-). A further rise of temperature up to about 20 degrees C gives evidence for the formation of a salt with the 1,1,1,2,3,6,6,6-octafluoro-2,4,4,5,5 -pentakis (trifluoromethyl) hex- an-3-ide anion. This intermediate decomposes at room temperature into the 1,1,1,3,5,5,5-heptafluoro-2,4-bis(trifluoromethyl)pentenide anion. The bis([15]crown-5)cesium salt, [Cs([15]crown-5)(2)][(CF3)(2)CCFC(CF3)(2)] has been characterized unambiguously as the stable final product of this reaction sequence. Thermal decomposition of this salt opens a convenient nontoxic route to obtain 1,1,3,3-tetrakis(trifluoromethyl)allene, (F3C)(2)C=C=C(CF3)(2).
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据