期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 3, 期 21, 页码 3905-3910出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b510535h
关键词
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An experimental (H-1 NMR) and theoretical (DFT) study of the ring-chain-ring isomerization of 3-(2-pyridyl)-[1,2,3]triazolo[1,5-a]pyrid-7-yl derivatives (A) into 6-{[1,2,3]triazolo[1,5-a]pyrid-3-yl}-2-pyridyl derivatives (B) has been carried out. Based on the calculations, a mechanism of several steps will be proposed. The experimental results as well as the calculations lead to the conclusion that the A-B ratio depends on the electronic properties of the substituents.
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