期刊
ORGANIC LETTERS
卷 7, 期 23, 页码 5261-5264出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol052121f
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资金
- FIC NIH HHS [U19 TW007401, U01 TW007401] Funding Source: Medline
Three diterpene-benzoate natural products, with novel carbon skeletons and an unusual proposed biosynthesis, were isolated from extracts of the Fijian red alga Callophycus serratus and identified by a combination of X-ray crystallographic, NMR, and mass spectral analyses. Bromophycolide A (1) displayed cytotoxicity against several human tumor cell lines via specific apoptotic cell death. This represents the first discovery of natural products incorporating a diterpene and benzoate skeleton into a macrolide system.
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