期刊
JOURNAL OF HAZARDOUS MATERIALS
卷 126, 期 1-3, 页码 1-7出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jhazmat.2005.05.044
关键词
1-hydroxybenzotriazoles; HOBt; 6-Cl-HOBt; TBTU; HOAt; explosive properties
1-Hydroxybenzotriazole and its derivatives are widely used as peptide coupling reagents. However, people are often not aware that such compounds show explosive properties when heated under defined confinement or when subjected to mechanical stimulus. 1-Hydroxybenzotriazole (HOBt) is able to propagate a detonation when a stronger booster is used. Sometimes explosive substances are desensitized to suppress their hazardous properties, yet depending on the amount and nature of desensitizer, the result is often not quite satisfactory.
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