期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 70, 期 23, 页码 9185-9190出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo0511546
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As demonstrated by H-1, C-13, and Ag-109 NMR, a pi-alkyne-Ag complex and then an alkynyl silver are in situ formed from alkyne and silver salt in conditions related to those used for Ag-catalyzed alkynylation or for Ag/Pd-catalyzed sp-sp(2) cross-coupling reactions. This finding allows for a rationale of the mechanisms of these reactions.
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