期刊
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
卷 585, 期 2, 页码 256-268出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jelechem.2005.09.001
关键词
digital simulation; liquid vertical bar liquid interface; water autoprotolysis; facilitated ion transfer; complex formation
In a previous paper [J. Electroanal. Chem. 578 (2005) 159] we have presented the general equations for a model of ion transfer reactions across the oil vertical bar water interface assisted by a neutral protonatable ligand. Our analysis focused mainly on the effect of water autoprotolysis on transfer processes. In this second part, cation transfer assisted by a protonatable ligand is described. The competitive reaction for a ligand between metal cation and proton is presented. The results are analyzed for different zones determined by the cation/ligand and proton/ligand concentration ratios. (c) 2005 Elsevier B.V. All rights reserved.
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