期刊
ANNUAL REVIEW OF PHYSICAL CHEMISTRY, VOL 63
卷 63, 期 -, 页码 45-64出版社
ANNUAL REVIEWS
DOI: 10.1146/annurev-physchem-032511-143755
关键词
Dirac equation; heavy-element chemistry; gold; lead-acid battery
Relativistic effects can strongly influence the chemical and physical properties of heavy elements and their compounds. This influence has been noted in inorganic chemistry textbooks for a couple of decades. This review provides both traditional and new examples of these effects, including the special properties of gold, lead-acid and mercury batteries, the shapes of gold and thallium clusters, heavy-atom shifts in NMR, topological insulators, and certain specific heats.
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