期刊
ANNUAL REVIEW OF PHYSICAL CHEMISTRY
卷 60, 期 -, 页码 61-83出版社
ANNUAL REVIEWS
DOI: 10.1146/annurev.physchem.59.032607.093651
关键词
metal ions; antibiotics; chromate; electrical double layer; carboxylic acid; interfacial acidities
资金
- U.S. Department of Energy [DE-FG02-06ER15787]
- National Science Foundation [CHE-0348873]
- Dow Chemical Company
This review discusses recent advances in the nonlinear optics of environmental interfaces. We discuss the quantitative aspects of the label-free approaches presented here and demonstrate that nonlinear optics has now assumed the role of a Swiss Army knife that can be used to dissect, with molecular detail, the fundamental and practical aspects of environmental interfaces and heterogeneous geochemical environments. In this work, nonlinear optical methods are applied to complex organic molecules, such as veterinary antibiotics, and to small inorganic anions and cations, such as nitrate and chromate, or cadmium, zinc, and manganese. The environmental implications of the thermodynamic, kinetic, spectroscopic, structural, and electrochemical data are discussed.
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