4.5 Article Proceedings Paper

Simulations of phase transitions in ionic systems

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JOURNAL OF PHYSICS-CONDENSED MATTER
卷 17, 期 45, 页码 S3205-S3213

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IOP PUBLISHING LTD
DOI: 10.1088/0953-8984/17/45/003

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A review of recent simulation work in the area of phase transitions in ionic systems is presented. The vapour-liquid transition for the restricted primitive model has been studied extensively in the past decade. The critical temperature is now known to excellent accuracy and the critical density to moderate accuracy. There is also strong simulation-based evidence that the model is in the Ising universality class. Discretized lattice versions of the model are reviewed. Other systems covered are size- and charge-asymmetric electrolytes, colloid-salt mixtures, realistic salt models and charged chains. Areas of future research needs are briefly discussed.

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