期刊
TETRAHEDRON LETTERS
卷 46, 期 47, 页码 8241-8244出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2005.09.077
关键词
photocleavable; photolabile; linker; o-nitrobenzyl; 2-nitrobenzyl; chemical proteomics; affinity support; UV LED
Linkers currently used in solid phase synthesis are generally short and hydrophobic, limiting their usefulness in biological systems. Herein, we describe a facile synthesis of a long, hydrophilic, o-nitrobenzyl photocleavable linker, suitable for constructing affinity supports for use in chemical proteomics. The rates of photolysis of the linker on exposure to UV light emitting diodes are reported. (c) 2005 Elsevier Ltd. All rights reserved.
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