期刊
ANNUAL REVIEW OF MATERIALS RESEARCH, VOL 43
卷 43, 期 -, 页码 359-386出版社
ANNUAL REVIEWS
DOI: 10.1146/annurev-matsci-071312-121623
关键词
crystal growth; shape prediction; spiral growth; morphology modeling; temperature cycling; structure-directing agents
资金
- Directorate For Engineering
- Div Of Chem, Bioeng, Env, & Transp Sys [1159746] Funding Source: National Science Foundation
Crystallization is an important separation and particle formation technique in the manufacture of high-value-added products. During crystallization, many physicochemical characteristics of the substance are established. Such characteristics include crystal polymorph, shape and size, chemical purity and stability, reactivity, and electrical and magnetic properties. However, control over the physical form of crystalline materials has remained poor, due mainly to an inadequate understanding of the basic growth and dissolution mechanisms, as well as of the influence of impurities, additives, and solvents on the growth rate of individual crystal faces. Crystal growth is a surface-controlled phenomenon in which solute molecules are incorporated into surface lattice sites to yield the bulk long-range order that characterizes crystalline materials. In this article, we describe some recent advances in crystal morphology engineering, with a special focus on a new mechanistic model for spiral growth. These mechanistic ideas are simple enough that they can be made to work and accurate enough that they are useful.
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