期刊
ANNUAL REVIEW OF MATERIALS RESEARCH, VOL 41
卷 41, 期 -, 页码 241-268出版社
ANNUAL REVIEWS
DOI: 10.1146/annurev-matsci-062910-100344
关键词
metal oxides; viologens; conjugated conducting polymers; metal complexes; Prussian blue
Electrochromic materials have the property of a change, evocation, or bleaching of color as effected either by an electron-transfer (redox) process or by a sufficient electrochemical potential. The main classes of electrochromic materials are surveyed here, with descriptions of representative examples from the metal oxides, viologens (in solution and as adsorbed or polymeric films), conjugated conducting polymers, metal coordination complexes (as polymeric, evaporated, or sublimed films), and metal hexacyanometallates. Examples of the applications of such electrochromic materials are included. Other materials aspects important for the construction of electrochromic devices include optically transparent electrodes, electrolyte layers, and device encapsulation. Commercial successes, current trends, and future challenges in electrochromic materials research and development are summarized.
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