期刊
JOURNAL OF ORGANOMETALLIC CHEMISTRY
卷 690, 期 24-25, 页码 5458-5466出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2005.07.097
关键词
benzothiazole carbenes ligands; catalysis; ionic liquids; palladium; C-C coupling
Pd-benzothiazol-2-ylidene complex 3 catalyzes efficiently the carbon-carbon coupling reactions in the ionic liquid tetrabutylammonium bromide (TBAB) as solvent. The IL does exert a striking influence on the reactivity and the stability of the catalyst. This is probably due to the formation, by reaction with TBAB, of an anionic and more nucleophilic complex surrounded by large tetrabutylammonium cation that would impede, by imposing a Coulombic barrier for collision, the formation of clusters growing further into catalytically inactive metal particles. On the contrary, ionic liquids with planar structures and poor nucleophilic anions like the [bmims], that form tight ion pairs, are barely efficient in influencing the reactivity and stability of the catalyst. (c) 2005 Elsevier B.V. All rights reserved.
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