期刊
PURE AND APPLIED CHEMISTRY
卷 77, 期 12, 页码 1985-1990出版社
WALTER DE GRUYTER GMBH
DOI: 10.1351/pac200577121985
关键词
tertiary phosphines; nucleophilic catalysts; allenoates; dipolarophiles; synthetic methodology
Allenoates or 2-alkynoates are known to react with tertiary phosphines to form the phosphine-substituted 1,3-dipoles, which can react with various substrates with the simultaneous elimination of the tertiary phosphine. The reaction is catalytic to the tertiary phosphine used. The investigation of the appropriate dipolarophiles and the further extension of this reaction are discussed.
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